You can use this trick to register an account with other domain name instead of hotmail.com domain.
1. Go to Windows Live ID overview page.
2. Click on the Sign-Up button.
3. Copy and paste the following code into the browser address bar and hit enter.
4, After you hit enter, there will be an alert saying “Success - additional domains added!”.
5. Now you can select the domain with which you want to register instead of hotmail.com only.

Thanks Cypherhackz
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Posted on November 11, 2006
Wow… Thanks for reminding me. Actually I read about it yesterday, but forgot to post it on my blog